Etiquette is a system of rules and conventions that regulate social and professional behavior. These norms are upheld by custom and group pressure rather than formal law; breaking them typically brings disapproval, not legal penalties.
Manners are the everyday expressions of courtesy and consideration toward other people—saying please and thank you, showing kindness, and putting others at ease. Good manners can be practiced without knowing every formal etiquette rule for a given setting.
In short, etiquette supplies the codified rules for particular situations, while manners are the personal habits of respect that make those rules feel genuine. Source: Etiquette — Encyclopaedia Britannica.